noun

definition

The branch of chemistry that involves the spatial arrangement of the atoms of molecules, and studies how this affects the physical and chemical properties of such species

definition

The effect of such spatial arrangement on the chemistry of a particular compound

Examples of stereochemistry in a Sentence

Even in such simple systems, controlling the stereochemistry at the benzylic position (crucial to materials properties) is problematic.

The system with C s has cis stereochemistry at the bicyclic ring junction, whilst that with C 2 symmetry has trans stereochemistry.

The team confirmed the stereochemistry of ptaquiloside from the X-ray structure of a derivative.

The system with C s has cis stereochemistry at the bicyclic ring junction, whilst that with C 2 symmetry has trans stereochemistry at the bicyclic ring junction, whilst that with C 2 symmetry has trans stereochemistry.

Details such as the absolute stereochemistry of tryptophan side chains, usually only available from high resolution X-ray crystallography, are also sometimes available.

We are also interested in controlling the relative stereochemistry of polymerisation using chiral organometallic catalysts.

The isomerism of crotonic and isocrotonic acids is to be explained on the assumption of a different spatial arrangement of the atoms in the molecule (see Stereochemistry).

The stereochemistry of each reaction also reflects its symmetry.

The InChI does not define the stereochemistry of the molecule.

The general principles of stereochemistry being discussed in Stereoisomerism (q.v.), we proceed to the synthesis of glucose and fructose and then to the derivation of their configurations.

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